Physics – Condensed Matter – Statistical Mechanics
Scientific paper
2010-02-05
Physics
Condensed Matter
Statistical Mechanics
Lecture notes. Fundamental Problems in Statistical Physics XII, Leuven, Aug 30 - Sept 12, 2009
Scientific paper
10.1016/j.physa.2010.01.001
For macroscopic systems, the second law of thermodynamics establishes an inequality between the amount of work performed on a system in contact with a thermal reservoir, and the change in its free energy. For microscopic systems, this result must be considered statistically, as fluctuations around average behavior become substantial. In recent years it has become recognized that these fluctuations satisfy a number of strong and unexpected relations, which remain valid even when the system is driven far from equilibrium. We discuss these relations, and consider what they reveal about the second law of thermodynamics and the nature of irreversibility at the microscale.
Boksenbojm Eliran
Jarzynski Christopher
Wynants Bram
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