Nonadditive hard-sphere fluid mixtures: A simple analytical theory

Details Nonadditive hard-sphere fluid mixtures: A simple analytical theory Nonadditive hard-sphere fluid mixtures: A simple analytical theory

2011-07-23

arxiv.org/abs/1107.4703v2

Phys. Rev. E 84, 041201 (2011)

Physics

Condensed Matter

Soft Condensed Matter

19 pages, 13 figures, 3 tables; v2: minor changes, supplemental material

Scientific paper

10.1103/PhysRevE.84.041201

We construct a non-perturbative fully analytical approximation for the thermodynamics and the structure of nonadditive hard-sphere fluid mixtures. The method essentially lies in a heuristic extension of the Percus-Yevick solution for additive hard spheres. Extensive comparison with Monte Carlo simulation data shows a generally good agreement, especially in the case of like-like radial distribution functions.

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