Physics – Condensed Matter – Statistical Mechanics
Scientific paper
2001-08-02
Phys. Rev. E 65 (2002) 011107.
Physics
Condensed Matter
Statistical Mechanics
Second one in a sequence of two (in the first, the formalism was developed). 12 pages REVTeX. 5 figures (eps). Submitted to Ph
Scientific paper
10.1103/PhysRevE.65.011107
A recent mode coupling theory of higher-order correlation functions is tested on a simple hard-sphere fluid system at intermediate densities. Multi-point and multi-time correlation functions of the densities of conserved variables are calculated in the hydrodynamic limit and compared to results obtained from event-based molecular dynamics simulations. It is demonstrated that the mode coupling theory results are in excellent agreement with the simulation results provided that dissipative couplings are included in the vertices appearing in the theory. In contrast, simplified mode coupling theories in which the densities obey Gaussian statistics neglect important contributions to both the multi-point and multi-time correlation functions on all time scales.
Schofield Jeremy
Zon Ramses van
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