Molecular ordering of precursor films during spreading of tiny liquid droplets

Physics – Condensed Matter

Scientific paper

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4 pages, revtex, no figures, complete file available from ftp://rock.helsinki.fi/pub/preprints/tft/ or at http://www.physics

Scientific paper

10.1103/PhysRevE.52.R2165

In this work we address a novel feature of spreading dynamics of tiny liquid droplets on solid surfaces, namely the case where the ends of the molecules feel different interactions to the surface. We consider a simple model of dimers and short chain--like molecules which cannot form chemical bonds with the surface. We study the spreading dynamics by Molecular Dynamics techniques. In particular, we examine the microscopic structure of the time--dependent precursor film and find that in some cases it can exhibit a high degree of local order. This order persists even for flexible chains. Our results suggest the possibility of extracting information about molecular interactions from the structure of the precursor film.

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