Molecular model for de Vries type smectic A - smectic C phase transition in liquid crystals

Physics – Condensed Matter – Soft Condensed Matter

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Submitted to Phys. Rev. Lett

Scientific paper

10.1103/PhysRevE.75.060701

We develop a theory of Smectic A - Smectic C phase transition with anomalously weak smectic layer contraction. We construct a phenomenological description of this transition by generalizing the Chen-Lubensky model. Using a mean-field molecular model, we demonstrate that a relatively simple interaction potential suffices to describe the transition. The theoretical results are in excellent agreement with experimental data.

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