Model of the electrochemical conversion of an undoped organic semiconductor film to a doped conductor film

Details Model of the electrochemical conversion of an undoped organic semiconductor film to a doped conductor film Model of the electrochemical conversion of an undoped organic semiconductor film to a doped conductor film

2009-09-16

arxiv.org/abs/0909.2961v1

Physics

Condensed Matter

Materials Science

4 pages, 3 figures

Scientific paper

We develop a model describing the electrochemical conversion of an organic semiconductor (specifically, the active material in a light-emitting electrochemical cell) from the undoped non-conducting state to the doped conducting state. The model takes into account both strongly concentration-dependent mobility and diffusion for the electronic charge carriers and the Nernst equation in the doped conducting regions. It is demonstrated that the experimentally observed doping front progression in light-emitting electrochemical cells can be accurately described with this model.

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