Model for the free-volume distributions of equilibrium fluids

Details Model for the free-volume distributions of equilibrium fluids Model for the free-volume distributions of equilibrium fluids

2006-06-01

arxiv.org/abs/cond-mat/0606044v1

J. Chem. Phys. 124, 214502 (2006)

Physics

Condensed Matter

Soft Condensed Matter

7 pages, 5 figures

Scientific paper

10.1063/1.2202354

We introduce and test via molecular simulation a simple model for predicting the manner in which interparticle interactions and thermodynamic conditions impact the single-particle free-volume distributions of equilibrium fluids. The model suggests a scaling relationship for the density-dependent behavior of the hard-sphere system. It also predicts how the second virial coefficients of fluids with short-range attractions affect their free-volume distributions.

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