Model Calculation of Electron-Phonon Couplings in a Dimer with a Non-Degenerate Orbital

Details Model Calculation of Electron-Phonon Couplings in a Dimer with a Non-Degenerate Orbital Model Calculation of Electron-Phonon Couplings in a Dimer with a Non-Degenerate Orbital

1999-04-28

arxiv.org/abs/cond-mat/9904405v2

Physics

Condensed Matter

Strongly Correlated Electrons

5 postscript figures

Scientific paper

10.1142/S0217979299003052

We evaluate all the electron-phonon couplings derived from the one-body electronic interactions, in both the adiabatic and extreme non-adiabatic limit, for a dimer with a non-degenerate orbital built from atomic wave functions of Gaussian shape. We find largely different values of the coupling parameters in the two cases, as well as different expressions of the corresponding terms in the Hamiltonian.

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