Microwave Spectroscopy of - Peroxide, CF_3OOCF_3

Details Microwave Spectroscopy of - Peroxide, CF_3OOCF_3 Microwave Spectroscopy of - Peroxide, CF_3OOCF_3

Jun 2010

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2010mss..conferh09k&link_type=abstract

"International Symposium On Molecular Spectroscopy, 65th Meeting, Held 21-25 June, 2010 at Ohio State University. http://molspec

Physics

Microwave (Rotational)

Scientific paper

The microwave spectrum of bis-(trifluoromethyl) peroxide, CF_3OOCF_3, was measured between 5 and 20 GHz frequency region. The spectrum of its 13C isotopologue was also recorded in natural abundance. All observed transitions were ambiguously assigned. The rotational and centrifugal distortion constants for the dominate CF_3OOCF_3 species are: A = 2806.6567(2) MHz, B = 795.3253(2) MHz, C = 790.3212(2) MHz, Δ_J = 68.0(3) Hz, ΔJK = 179(1) Hz, and δ_J = -0.44(9) Hz. The ab initio and the density functional theory level of calculations were performed to optimize the molecular geometry and to predict the spectroscopic constants. The theoretical predictions are in moderate agreement with the experimental measurements.

Affiliated with

Also associated with

No associations

Rating

Microwave Spectroscopy of - Peroxide, CF_3OOCF_3 does not yet have a rating. At this time, there are no reviews or comments for this scientific paper.

If you have personal experience with Microwave Spectroscopy of - Peroxide, CF_3OOCF_3, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Microwave Spectroscopy of - Peroxide, CF_3OOCF_3 will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFWR-SCP-O-1592465