Microscopic theory of multipole ordering in NpO2

Physics – Condensed Matter – Strongly Correlated Electrons

Scientific paper

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5 pages, 2 figures

Scientific paper

10.1103/PhysRevB.71.140404

In order to examine the mysterious ordered phase of NpO2 from a microscopic viewpoint, we investigate an f-electron model on an fcc lattice constructed based on a j-j coupling scheme. First, an effective model with multipole interactions is derived in the strong-coupling limit. Numerical analysis of the model clearly indicates that the interactions for \Gamma_{4u} and \Gamma_{5u} moments are relevant to the ground state. Then, by applying mean-field theory to the simplified model including only such interactions, we conclude that longitudinal triple-q \Gamma_{5u} octupole order is realized in NpO2 through the combined effects of multipole interactions and anisotropy of the \Gamma_{5u} moment.

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