Physics – Condensed Matter – Soft Condensed Matter
Scientific paper
2008-01-18
Physics
Condensed Matter
Soft Condensed Matter
12 pages, 11 figures. Note that some figures are extremely low quality to meet arXiv's file size limits
Scientific paper
10.1063/1.2913522
Polymers with both soluble and insoluble blocks typically self-assemble into micelles, aggregates of a finite number of polymers where the soluble blocks shield the insoluble ones from contact with the solvent. Upon increasing concentration, these micelles often form gels that exhibit crystalline order in many systems. In this paper, we present a study of both the dynamics and the equilibrium properties of micellar crystals of triblock polymers using molecular dynamics simulations. Our results show that equilibration of single micelle degrees of freedom and crystal formation occurs by polymer transfer between micelles, a process that is described by transition state theory. Near the disorder (or melting) transition, bcc lattices are favored for all triblocks studied. Lattices with fcc ordering are also found, but only at lower kinetic temperatures and for triblocks with short hydrophilic blocks. Our results lead to a number of theoretical considerations and suggest a range of implications to experimental systems with a particular emphasis on Pluronic polymers.
Anderson Alan J.
Lorenz Christan D.
Travesset Alex
No associations
LandOfFree
Micellar Crystals in Solution from Molecular Dynamics Simulations does not yet have a rating. At this time, there are no reviews or comments for this scientific paper.
If you have personal experience with Micellar Crystals in Solution from Molecular Dynamics Simulations, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Micellar Crystals in Solution from Molecular Dynamics Simulations will most certainly appreciate the feedback.
Profile ID: LFWR-SCP-O-691364