Metastable quasi-one-dimensional ensembles of nitrogen clusters N_8

Details Metastable quasi-one-dimensional ensembles of nitrogen clusters N_8 Metastable quasi-one-dimensional ensembles of nitrogen clusters N_8

2002-04-29

arxiv.org/abs/cond-mat/0204605v1

Phys. Low-Dim. Struct. 1/2 (2002) 135

Physics

Condensed Matter

Mesoscale and Nanoscale Physics

3 pages, 4 ps figures

Scientific paper

10.1134/1.1575351

By means of ab initio and tight-binding calculations it is shown that metastable nitrogen clusters N_8 (boats) can form quasi-one-dimensional ensembles in which the nearest clusters N_8 are bound to each other by covalent bonds. Those ensembles are characterized by rather high energy barriers (~ 0.3 eV) that prevent the fission of the ensembles into isolated N_8 clusters and/or N_2 molecules.

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