Physics
Scientific paper
Apr 1981
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1981jphb...14.1353m&link_type=abstract
Journal of Physics B - Atomic and Molecular Physics, vol. 14, Apr. 28, 1981, p. 1353-1361. Research supported by the U.S. Depart
Physics
53
Beam Interactions, Gas Dissociation, Interstellar Gas, Interstellar Space, Ion Recombination, Methane, Cross Sections, Electron Beams, Electron Energy, Ion Beams
Scientific paper
The dissociative recombination of the methane-derived group, CH(+),...,CH5(+), has been measured over the centre-of-mass energy interval 0.03 to 2 eV. Assuming a Maxwellian distribution of the electron velocities, the derived rate coefficients for CH(+),...,CH5(+) at 100 K are, respectively, 5, 8.7, 12, 12.8 and 12.8 x 10 to the -7th cu cm/s. The recombination cross section for the diatomic ion CH(+) is large. This has far reaching consequences for the theories of molecular formation in interstellar clouds. The cross sections for the polyatomics CH(+),...,CH5(+) are also large and roughly equal in magnitude. Like CH(+) they exhibit a close to E to the -1st energy dependence below 0.1 eV. For CH3(+), CH4(+) and CH5(+) the slope of the cross sections increases above 0.1 eV.
Dangelo V. S.
Defrance Pierre
Froelich H. R.
McGowan Wm. J.
Mitchell J. B. A.
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