Melting of the Na layers in solid Na0.8CoO2

Physics – Condensed Matter – Strongly Correlated Electrons

Scientific paper

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4 pages, 4 figures

Scientific paper

10.1103/PhysRevLett.102.056401

Data of 23Na NMR spectra- and relaxation measurements are interpreted as suggesting that, upon increasing temperature the Na layers in Na0.8CoO2 adopt a 2D liquid state at T=291 K. The corresponding first order phase transition is preceded by a rapidly increasing mobility and diffusion of Na ions above 200K. Above 291 K the 23Na NMR response is similar to that previously observed in superionic conductors with planar Na layers.

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