Physics – Condensed Matter – Statistical Mechanics
Scientific paper
2005-11-16
J. Magn. Reson. 179, 11 (2006)
Physics
Condensed Matter
Statistical Mechanics
28 pages, 15 embedded .eps figures, Elsevier preprint format
Scientific paper
10.1016/j.jmr.2005.10.011
It is shown that the diagrammatic cluster expansion technique for equilibrium averages of spin operators may be straightforwardly extended to the calculation of time-dependent correlation functions of spin operators. We use this technique to calculate exactly the first two non-vanishing moments of the spin-spin and energy-energy correlation functions of the XY model with arbitrary couplings, in the long-wavelength, infinite temperature limit appropriate for spin diffusion. These moments are then used to estimate the magnetization and spin-spin energy diffusion coefficients of the model using a phenomenological theory of Redfield. Qualitative agreement is obtained with recent experiments measuring diffusion of dipolar energy in calcium fluoride.
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