Physics – Condensed Matter – Strongly Correlated Electrons
Scientific paper
2010-07-22
Phys. Rev. B 82, 094453 (2010)
Physics
Condensed Matter
Strongly Correlated Electrons
6 pages, 6 figures
Scientific paper
V2O3 nanocrystals can be synthesized through hydrothermal reduction of VO(OH)2 using hydrazine as a reducing agent. Addition of different ligands to the reaction produces nanoparticles, nanorods and nanoplatelets of different sizes. Small nanoparticles synthesized in this manner show suppression of the magnetic phase transition to lower temperatures. Using muon spin relaxation spectroscopy and synchrotron x-ray diffraction, it is determined that the volume fraction of the high-temperature phase, characterized by a rhombohedral structure and paramagnetism, gradually declines with decreasing temperature, in contrast to the sharp transition observed in bulk V2O3.
Aczel A. A.
Billinge Simon J. L.
Blagojevic V. A.
Brus Louis E.
Carlo Jeremy P.
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