Low Symmetry Phase in (001) BiFeO$_3$ Epitaxial Constrained Thin Films

Details Low Symmetry Phase in (001) BiFeO$_3$ Epitaxial Constrained Thin Films Low Symmetry Phase in (001) BiFeO$_3$ Epitaxial Constrained Thin Films

2005-01-27

arxiv.org/abs/cond-mat/0501675v1

Physics

Condensed Matter

Materials Science

Scientific paper

10.1063/1.1924891

The lattice of (001)-oriented BiFeO$_3$ epitaxial thin film has been identified by synchrotron x-ray diffraction. By choosing proper scattering zones containing the fixed (001) reflection, we have shown that low-symmetry phases similar to a $M_A$ phase exist in the thin film at room temperature. These results demonstrate a change in phase stability from rhombohedral in bulk single crystals, to a modified monoclinic structure in epitaxial thin films.

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