Physics – Condensed Matter – Strongly Correlated Electrons
Scientific paper
2010-11-04
Phys.Rev. B 83, 174419 (2011)
Physics
Condensed Matter
Strongly Correlated Electrons
5 pages, 7 figures
Scientific paper
1H nuclear magnetic resonance (NMR) measurements in [YPc2]0, an organic compound formed by radicals stacking along chains, are presented. The temperature dependence of the macroscopic susceptibility, of the NMR shift and of the spin-lattice relaxation rate 1/T1 indicate that the unpaired electron spins are not delocalized but rather form a S=1/2 antiferromagnetic chain. The exchange couplings estimated from those measurements are all in quantitative agreement. The low-energy spin dynamics can be described in terms of diffusive processes and the temperature dependence of the corresponding diffusion constant suggests that a spin-gap around 1 K might be present in this compound.
Branzoli F.
Carretta Pietro
Filibian M.
Klyatskaya S.
Ruben M.
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