Long-range electrostatic interactions between like-charged colloids: steric and confinement effects

Details Long-range electrostatic interactions between like-charged colloids: steric and confinement effects Long-range electrostatic interactions between like-charged colloids: steric and confinement effects

1999-09-29

arxiv.org/abs/cond-mat/9909420v1

Phys. Rev. E 60, 6530 (1999).

Physics

Condensed Matter

Soft Condensed Matter

5 pages, 1 figure, to appear in Physical Review E

Scientific paper

10.1103/PhysRevE.60.6530

Within the framework of a Modified Poisson-Boltzmann theory accounting for steric effects of microions, we prove analytically that the effective pair interactions between like-charge colloids immersed in a confined electrolyte are repulsive. Our approach encompasses and extends previously known results to the case of complete confinement, and further incorporates the finite size of the microions which is absent in the standard Poisson-Boltzmann theory.

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