Physics – Condensed Matter – Statistical Mechanics
Scientific paper
2007-04-30
Physics
Condensed Matter
Statistical Mechanics
30 pages, 5 figures
Scientific paper
10.1080/00268970701420524
Two liquid state theories, the self-consistent Ornstein-Zernike equation (SCOZA) and the hierarchical reference theory (HRT) are shown, by comparison with Monte Carlo simulations, to perform extremely well in predicting the liquid-vapour coexistence of the hard core Yukawa (HCY) fluid when the interaction is long range. The long range of the potential is treated in the simulations using both an Ewald sum and hyperspherical boundary conditions. In addition, we present an analytical optimised mean field theory which is exact in the limit of an infinitely long range interaction. The work extends a previous one by Caccamo et al [Phys. Rev. E,60, 5533 (1999)] for short range interactions.
Caillol Jean-Michel
Scholl-Paschinger Elisabeth
Verso Federica Lo
Weis Jean-Jacques
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