Linear aggregation beyond isodesmic symmetry

Details Linear aggregation beyond isodesmic symmetry Linear aggregation beyond isodesmic symmetry

2008-06-20

arxiv.org/abs/0806.3438v1

Journal of Chemical Physics 130, 045101 (2009)

Physics

Condensed Matter

Soft Condensed Matter

10 pages, 2 figures

Scientific paper

10.1063/1.3063099

Exactly solvable models of linear aggregation have been known since Ising's seminal one-dimensional model. This model is defined by a unique nearest-neighbour bond strength that is independent of the length of the cluster; known as isodesmic symmetry. Linear aggregation in real systems has often been associated with broken isodesmic symmetry. Here we show that important examples can be mapped to a class of one-dimensional models that are also exactly solvable.

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