Landau theory applied to phase transitions in calcium orthotungstate and isostructural compounds

Physics – Condensed Matter – Materials Science

Scientific paper

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14 pages, 3 figures

Scientific paper

10.1209/0295-5075/77/56001

The pressure-driven tetragonal-to-monoclinic phase transition in CaWO4 and
related scheelite-structured orthotungstates is analysed in terms of
spontaneous strains. Based upon our previous high-pressure x-ray diffraction
results and the Landau theory, it is suggested that the
scheelite-to-fergusonite transition is of second order in nature.

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