Lamellar phase stability in diblock copolymers under reciprocating shear flows

Details Lamellar phase stability in diblock copolymers under reciprocating shear flows Lamellar phase stability in diblock copolymers under reciprocating shear flows

2001-09-04

arxiv.org/abs/cond-mat/0109068v1

Macromolecules 35, 4183 (2002).

Physics

Condensed Matter

Soft Condensed Matter

22 pages, 5 figures

Scientific paper

10.1021/ma011586s

A mesoscopic model of a diblock copolymer is used to study the stability of a uniform lamellar phase under a reciprocating shear flow. Approximate viscosity contrast between the microphases is allowed through a linear dependence of the (Newtonian) shear viscosity on monomer composition. We first show that viscosity contrast does not affect the composition of the base lamellar phase in an unbounded geometry, and that it only couples weakly to long wavelength perturbations. A perturbative analysis is then presented to address the stability of uniform lamellar structures under long wavelength perturbations by self-consistently solving for the composition and velocity fields of the perturbations. Stability boundaries are obtained as functions of the physical parameters of the polymer, the parameters of the flow and the initial orientation of the lamellae. We find that all orientations are linearly stable within specific ranges of parameters, but that the perpendicular orientation is generally stable within a larger range than the parallel orientation. Secondary instabilities are both of the Eckhaus type (longitudinal) and zig-zag type (transverse). The former is not expected to lead to re-orientation of the lamella, whereas in the second case the critical wavenumber is typically found to be along the perpendicular orientation.

Affiliated with

Also associated with

No associations

Rating

Lamellar phase stability in diblock copolymers under reciprocating shear flows does not yet have a rating. At this time, there are no reviews or comments for this scientific paper.

If you have personal experience with Lamellar phase stability in diblock copolymers under reciprocating shear flows, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Lamellar phase stability in diblock copolymers under reciprocating shear flows will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFWR-SCP-O-714940