Kinetics of non-ionic surfactant adsorption at a fluid-fluid interface from a micellar solution

Details Kinetics of non-ionic surfactant adsorption at a fluid-fluid interface from a micellar solution Kinetics of non-ionic surfactant adsorption at a fluid-fluid interface from a micellar solution

2005-04-12

arxiv.org/abs/cond-mat/0504296v2

Journal of Chemical Physics 123 (2005) 126101

Physics

Condensed Matter

Soft Condensed Matter

4 pages

Scientific paper

10.1063/1.2036968

The kinetics of non-ionic surfactant adsorption at a fluid-fluid interface from a micellar solution is considered theoretically. Our model takes into account the effect of micelle relaxation on the diffusion of the free surfactant molecules. It is shown that non-ionic surfactants undergo either a diffusion or a kinetically limited adsorption according to the characteristic relaxation time of the micelles. This gives a new interpretation for the observed dynamical surface tension of micellar solutions.

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