Physics – Condensed Matter – Soft Condensed Matter
Scientific paper
2004-02-12
Physics
Condensed Matter
Soft Condensed Matter
8 Figures. To be published in Phys. Rev. E. For more information see http://www.elsie.brandeis.edu
Scientific paper
10.1103/PhysRevE.69.051702
We present an experimental study of the isotropic-nematic phase transition in an aqueous mixture of charged semi-flexible rods (fd virus) and neutral polymer (Dextran). A complete phase diagram is measured as a function of ionic strength and polymer molecular weight. At high ionic strength we find that adding polymer widens the isotropic-nematic coexistence region with polymers preferentially partitioning into the isotropic phase, while at low ionic strength the added polymer has no effect on the phase transition. The nematic order parameter is determined from birefringence measurements and is found to be independent of polymer concentration (or equivalently the strength of attraction). The experimental results are compared with the existing theoretical predictions for the isotropic-nematic transition in rods with attractive interactions.
Adams Marie
Dogic Zvonimir
Fraden Seth
Grelet Eric
Purdy Kirstin
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