Intermolecular Association Complexes of 1,3-CYCLOHEXANEDIONE: Probing of Keto-Enol Tautomeric Equilibria in Cold Inert Gas Matrix, Solution and Vapor Phase by Infrared Spectroscopy and Quantum Chemistry Study

Details Intermolecular Association Complexes of 1,3-CYCLOHEXANEDIONE: Probing of Keto-Enol Tautomeric Equilibria in Cold Inert Gas Matrix, Solution and Vapor Phase by Infrared Spectroscopy and Quantum Chemistry Study Intermolecular Association Complexes of 1,3-CYCLOHEXANEDIONE: Probing of Keto-Enol Tautomeric Equilibria in Cold Inert Gas Matrix, Solution and Vapor Phase by Infrared Spectroscopy and Quantum Chemistry Study

Jun 2011

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2011mss..confemg12b&link_type=abstract

"International Symposium On Molecular Spectroscopy, 66th Meeting, Held 20-24 June, 2011 at Ohio State University. http://molspec

Physics

Infrared/Raman

Scientific paper

Cyclic β-diketo compounds are known to show markedly different physical and chemical properties compared to their linear counterparts. 1,3-cyclohexanedione, the simplest molecule among the cyclic variants was found to exist exclusively in ketoenolic form in crystal whereas appreciable amount of diketo tautomer was identified in chloroform solution. We have studied this system by means of infrared spectroscopy to elucidate its tautomeric behavior under different environmental as well as thermal conditions ranging from solid argon matrix at 8 K to carbon tetrachloride and chloroform solution at room temperature and low pressure vapor at 330 K. Besides, we have monitored its homodimeric complexes and the effect of weak C-H---O hydrogen bonding on the keto-enol tautomeric equilibria. The potential energy surface of the ground electronic state has been computed by means of electronic structure calculation to corroborate the experimental findings.

Affiliated with

Also associated with

No associations

Rating

Intermolecular Association Complexes of 1,3-CYCLOHEXANEDIONE: Probing of Keto-Enol Tautomeric Equilibria in Cold Inert Gas Matrix, Solution and Vapor Phase by Infrared Spectroscopy and Quantum Chemistry Study does not yet have a rating. At this time, there are no reviews or comments for this scientific paper.

If you have personal experience with Intermolecular Association Complexes of 1,3-CYCLOHEXANEDIONE: Probing of Keto-Enol Tautomeric Equilibria in Cold Inert Gas Matrix, Solution and Vapor Phase by Infrared Spectroscopy and Quantum Chemistry Study, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Intermolecular Association Complexes of 1,3-CYCLOHEXANEDIONE: Probing of Keto-Enol Tautomeric Equilibria in Cold Inert Gas Matrix, Solution and Vapor Phase by Infrared Spectroscopy and Quantum Chemistry Study will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFWR-SCP-O-999731