Infrared properties of $θ$-type ET charge-transfer salts: $θ$-ET$_2$CsZn(SCN)$_4$ vs $θ$-ET$_2$RbZn(SCN)$_4$

Details Infrared properties of $θ$-type ET charge-transfer salts: $θ$-ET$_2$CsZn(SCN)$_4$ vs $θ$-ET$_2$RbZn(SCN)$_4$ Infrared properties of $θ$-type ET charge-transfer salts: $θ$-ET$_2$CsZn(SCN)$_4$ vs $θ$-ET$_2$RbZn(SCN)$_4$

2002-11-12

arxiv.org/abs/cond-mat/0211226v1

Physics

Condensed Matter

Strongly Correlated Electrons

2 pages, to be published in Synthetic Metal (Proceedings of International Conference on Science and Technology of Synthetic Me

Scientific paper

We performed polarized far-infrared reflectance measurements at different temperatures on $\theta$-ET$_2$RbZn(SCN)$_4$ and $\theta$-ET$_2$CsZn(SCN)$_4$, two typical charge-transfer salts in a series of isostructural $\theta$-ET$_2$MM'(SCN)$_4$. The measurements revealed distinct differences in both electronic and vibronic spectra, which provides a clue towards understanding the different metal-insulator transitions of the two salts.

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