Physics – Condensed Matter – Statistical Mechanics
Scientific paper
2011-11-29
Physics
Condensed Matter
Statistical Mechanics
1 + 16 Page, LaTex, 11 eps figures
Scientific paper
We study information geometry of the thermodynamics of first and second order phase transitions, and beyond criticality, in magnetic and liquid systems. We establish a universal microscopic characterization of such phase transitions via the equality of correlation lengths $\xi$ in coexisting phases, where $\xi$ is related to the scalar curvature of the equilibrium thermodynamic state space. The 1-D Ising model, and the mean-field Curie-Weiss model are discussed, and we show that information geometry correctly describes the phase behavior for the latter. The Widom lines for these systems are also established. We further study a simple model for the thermodynamics of liquid-liquid phase co-existence, and show that our method provides a simple and direct way to obtain its phase behavior and the locations of the Widom lines. Our analysis points towards multiple Widom lines in liquid systems.
Dey Anshuman
Roy Pratim
Sarkar Tapobrata
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