Physics – Condensed Matter – Mesoscale and Nanoscale Physics
Scientific paper
2011-09-29
Physics
Condensed Matter
Mesoscale and Nanoscale Physics
8 pages, 4 figures
Scientific paper
Porphyrin molecules can form stable single molecule junctions without anchoring groups. Adding thiol end groups and pyridine axial groups yields more stable junctions with an increased spread in low-bias conductance. This is a result of different bridging geometries during breaking, the stability of which is demonstrated in time-dependent conductance measurements. This is in strong contrast with rod like molecules which show one preferential binding geometry.
Briza Tomas
der Zant Herre S. J. van
Dulic Diana
Eelkema Rienk
Kaplanek Robert
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