Incommensurate Charge Order Phase in Fe2OBO3 due to Geometrical Frustration

Physics – Condensed Matter – Strongly Correlated Electrons

Scientific paper

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4 p., 5 fig.; v2: slightly expanded introduction + minor changes. PRL in print

Scientific paper

10.1103/PhysRevLett.99.256402

The temperature dependence of charge order in Fe2OBO3 was investigated by resistivity and differential scanning calorimetry measurements, Mossbauer spectroscopy, and synchrotron x-ray scattering, revealing an intermediate phase between room temperature and 340 K, characterized by coexisting mobile and immobile carriers, and by incommensurate superstructure modulations with temperature-dependent propagation vector (1/2,0,tau). The incommensurate modulations arise from specific anti-phase boundaries with low energy cost due to geometrical charge frustration.

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