Physics – Condensed Matter – Materials Science
Scientific paper
2010-12-07
Chemistry of Materials, Vol. 22, Pg 6467-6473 (2010)
Physics
Condensed Matter
Materials Science
24 pages, 7 figures, 3 tables
Scientific paper
10.1021/cm103088e
The triple "magnetic-transport-structural" transition versus temperature in three series of "114" cobaltites - Y1-xYbxBaCo4O7, Y1-xCaxBaCo4O7 and Yb1-xCaxBaCo4O7 - has been studied using magnetic, transport and differential scanning calorimetric measurements. The effect of the size mismatch {\sigma}2, due to cationic disordering at the Ln sites upon such a transition is shown for the first time in a triangular lattice. We show that increasing
Caignaert Vincent
Pralong Valerie
Raveau Bernard
Sarkar Tapati
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