Hysteresis in an Electrochemical System: Br Electrodeposition on Ag(100)

Details Hysteresis in an Electrochemical System: Br Electrodeposition on Ag(100) Hysteresis in an Electrochemical System: Br Electrodeposition on Ag(100)

2000-06-26

arxiv.org/abs/cond-mat/0006399v1

In Computer Simulation Studies in Condensed Matter Physics XIII, edited by D. P. Landau, S. P. Lewis, and H. B. Sch\"uttler, S

Physics

Condensed Matter

Materials Science

7 pages, 4 figures. S.J. Mitchell, P.A. Rikvold, G. Brown, in: Computer Simulation Studies in Condensed-Matter Physics XIII, E

Scientific paper

We examine hysteresis in cyclic voltammetry of Br electrosorption onto single-crystal Ag(100) by dynamic Monte Carlo simulations. At room temperature, this system displays a second-order phase transition from a low-coverage disordered phase to a doubly degenerate $c (2 \times 2)$ phase. The electrochemical potential is ramped back and forth across the phase transition, linearly in time, and the phase lag between the response of the adlayer and the potential is observed to depend on the sweep rate. The hysteresis in this system is caused by slow ordering/disordering kinetics and critical slowing-down.

Affiliated with

Also associated with

No associations

Rating

Hysteresis in an Electrochemical System: Br Electrodeposition on Ag(100) does not yet have a rating. At this time, there are no reviews or comments for this scientific paper.

If you have personal experience with Hysteresis in an Electrochemical System: Br Electrodeposition on Ag(100), we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Hysteresis in an Electrochemical System: Br Electrodeposition on Ag(100) will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFWR-SCP-O-34325