Hydrogen Absorption at Room Temperature in Nanoscale Titanium Benzene Complexes

Details Hydrogen Absorption at Room Temperature in Nanoscale Titanium Benzene Complexes Hydrogen Absorption at Room Temperature in Nanoscale Titanium Benzene Complexes

2009-04-15

arxiv.org/abs/0904.2378v1

Physics

Condensed Matter

Mesoscale and Nanoscale Physics

3 figures

Scientific paper

In this letter we report the first room temperature gravimetric measurements of hydrogen absorption in nanoscale titanium-benzene complexes formed by laser ablation in a benzene atmosphere in a UHV chamber. We are able to obtain a 6% by weight absorption as predicted by recent density functional theory based calculations under the conditions of low benzene pressure (35 milli-torr) and for sub-monolayer samples. For samples synthesized under higher benzene pressures we find a systematic degradation of the hydrogen absorption.

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