High resolution infrared spectrum of methyleneimine, CH2NH, in the 3 micron region

Details High resolution infrared spectrum of methyleneimine, CH2NH, in the 3 micron region High resolution infrared spectrum of methyleneimine, CH2NH, in the 3 micron region

Sep 1985

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1985jchph..83.2091h&link_type=abstract

Journal of Chemical Physics (ISSN 0021-9606), vol. 83, Sept. 1, 1985, p. 2091-2096. Research supported by the Royal Society of L

Physics

Chemical Physics

12

Imines, Infrared Spectroscopy, Methylene, Molecular Spectroscopy, Ground State, High Resolution, Molecular Rotation, Spectral Bands

Scientific paper

The infrared spectrum of the short-lived methyleneimine, CH2NH, was obtained in the gas phase with a resolution of about 0.01 per cm from 2800 to 3200 per cm, using the Kitt Peak National Observatory Solar Fourier Transform Spectrometer. The nu-2 band and the high order Coriolis coupled nu-3 and 2nu-5 bands have been analyzed rotationally. Several hundred transitions have been fitted and accurate band origins and rotational constants have been determined for each of the bands.

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