Physics – Chemical Physics
Scientific paper
Sep 1985
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1985jchph..83.2078h&link_type=abstract
Journal of Chemical Physics (ISSN 0021-9606), vol. 83, Sept. 1, 1985, p. 2078-2090. Research supported by the Academy of Finland
Physics
Chemical Physics
23
Imines, Infrared Spectroscopy, Methylene, Molecular Spectroscopy, Fourier Transformation, High Resolution, Interstellar Matter, Molecular Rotation, Wave Functions
Scientific paper
The short lived molecule, methyleneimine, CH2NH is of considerable interest as the simplest member of the imine family. Kirchoff et al. (1973) have identified the species in the gas phase by microwave spectroscopy. This identification provided a basis for the subsequent detection of CH2NH in the interstellar dust clouds. The present paper has the objective to discuss the reasons for the complexity of the spectrum of CH2NH in the 10 micron region, and to present a detailed analysis of the high resolution Fourier transform spectrum. Attention is given to experimental aspects, the observed spectra, a theoretical model, and a rotational analysis. It is found that the complexity of the spectrum is due primarily to the low symmetry, the large values of the Coriolis coupling constants, and the small separation of the vibrational states which are being coupled.
Duxbury G.
Halonen Lauri
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