High-pressure synthesis of rock salt LiMeO2-ZnO (Me = Fe3+, Ti3+) solid solutions

Details High-pressure synthesis of rock salt LiMeO2-ZnO (Me = Fe3+, Ti3+) solid solutions High-pressure synthesis of rock salt LiMeO2-ZnO (Me = Fe3+, Ti3+) solid solutions

2011-01-07

arxiv.org/abs/1101.1386v1

High Pressure Research, 31 [2] 304-309 (2011)

Physics

Condensed Matter

Materials Science

11 pages, 3 figures, 1 table

Scientific paper

10.1080/08957959.2011.560844

Metastable LiMeO2-ZnO (Me = Fe3+, Ti3+) solid solutions with rock salt crystal structure have been synthesized by solid state reaction of ZnO with LiMeO2 complex oxides at 7.7 GPa and 1350-1450 K. Structure, phase composition, thermal stability and thermal expansion of the recovered samples have been studied by X-ray diffraction with synchrotron radiation. At ambient pressure rock salt LiMeO2-ZnO solid solutions are kinetically stable up to 670-800 K depending on the composition.

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