High pressure synthesis of FeO-ZnO solid solutions with rock salt structure: in situ X-ray diffraction studies

Details High pressure synthesis of FeO-ZnO solid solutions with rock salt structure: in situ X-ray diffraction studies High pressure synthesis of FeO-ZnO solid solutions with rock salt structure: in situ X-ray diffraction studies

2011-02-03

arxiv.org/abs/1102.0626v1

High Pressure Research, 30 [1] 39-43 (2010)

Physics

Condensed Matter

Materials Science

9 pages, 2 figures, 1 table

Scientific paper

10.1080/08957950903550236

X-ray diffraction with synchrotron radiation has been used for the first time to study chemical interaction in the FeO-ZnO system at 4.8 GPa and temperatures up to 1300 K. Above 750 K, the chemical reaction between FeO and ZnO has been observed that resulted in the formation of rock salt (rs) Fe1-xZnxO solid solutions (0.3 \leq x \leq 0.85). The lattice parameters of these solid solutions have been in situ measured as a function of temperature under pressure, and corresponding thermal expansion coefficients have been calculated.

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