Physics – Condensed Matter – Strongly Correlated Electrons
Scientific paper
2006-03-02
J. Phys.: Condens. Matter 18 (2006) 11195\^a?"11202.
Physics
Condensed Matter
Strongly Correlated Electrons
4 pages, 3 figures
Scientific paper
10.1088/0953-8984/18/49/012
Resonant soft x-ray Bragg diffraction at the Dy M4,5 edges has been exploited to study Dy multipole motifs in DyB2C2. Our results are explained introducing the intra-atomic quadrupolar interaction between the core 3d and valence 4f shell. This allows us to determine for the first time higher order multipole moments of dysprosium $4f$ electrons and to draw their precise charge density. The Dy hexadecapole and hexacontatetrapole moment have been estimated at -20% and +30% of the quadrupolar moment, respectively. No evidence for the lock-in of the orbitals at T_N has been observed, in contrast to earlier suggestions. The multipolar interaction and the structural transition cooperate along c but they compete in the basal plane explaining the canted structure along [110].
Balcar E.
der Laan van G.
Kikkawa Akiko
Lovesey Stephen W.
Mulders A. M.
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