H(II) centers in natural silica under repeated UV laser irradiations

Physics – Condensed Matter – Materials Science

Scientific paper

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Submitted to Journal of Non Crystalline Solids

Scientific paper

10.1016/j.jnoncrysol.2005.04.012

We investigated the kinetics of H(II) centers (=Ge'-H) in natural silica under repeated 266nm UV irradiations performed by a Nd:YAG pulsed laser. UV photons temporarily destroy these paramagnetic defects, their reduction being complete within 250 pulses. After re-irradiation, H(II) centers grow again, and the observed recovery kinetics depends on the irradiation dose; multiple 2000 pulses re-irradiations induce the same post-irradiation kinetics of H(II) centers after each exposure cycle. The analysis of these effects allows us to achieve a deeper understanding of the dynamics of the centers during and after laser irradiation.

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