Physics – Condensed Matter – Superconductivity
Scientific paper
2001-05-29
J. Phys. Soc. Jpn. vol70 (2001) pp.2255-2258
Physics
Condensed Matter
Superconductivity
9 pages, 5 figures and 1 table
Scientific paper
10.1143/JPSJ.70.2255
Here we report the growth of sub-millimeter MgB2 single crystals of various shapes under high pressure in Mg-B-N system. Structure refinement using a single-crystal X-ray diffraction analysis gives lattice parameters a=3.0851(5) A and c=3.5201(5) A with small reliability factors (Rw =0.025, R=0.018), which enables us to analyze the Fourier and Fourier difference maps. The maps clearly show the B sp2 orbitals and covalency of the B-B bonds. The sharp superconducting transitions at Tc =38.1-38.3K were obtained in both magnetization (DTc =0.6K) and resistivity (DTc <0.3K) measurements. Resistivity measurements with magnetic fields applied parallel and perpendicular to the Mg and B sheets reveal the anisotropic nature of this compound, with upper critical field anisotropy ratio of about 2.7.
Eltsev Yu.
Lee Seongsu
Masui Takahiko
Mori Hatsumi
Tajima Setsuko
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