Physics – Condensed Matter – Strongly Correlated Electrons
Scientific paper
2010-02-13
Physics
Condensed Matter
Strongly Correlated Electrons
9 pages, 7 figures. to be published in J. Phys. Soc. Jpn. Vol. 79, No. 4
Scientific paper
Motivated by recent chemical attempts at assembling halogen-bridged transition-metal complexes within a nanotube, we model and characterize a platinum-halide triangular prism in terms of a Peierls-Hubbard Hamiltonian. Based on a group-theoretical argument, we reveal a variety of valence arrangements, including heterogeneous or partially metallic charge-density-wave states. Quantum and thermal phase competitions are numerically demonstrated with particular emphasis on novel insulator-to-metal and insulator-to-insulator transitions under doping, the former of which is of the first order, while the latter of which is of the second order.
Ohara Jun
Ozaki Masa-aki
Yamamoto Shoji
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