Physics – Condensed Matter – Materials Science
Scientific paper
2011-01-08
Physics
Condensed Matter
Materials Science
accepted in Nanoscale Research Letters; 16 pages, 4 figures, 2 tables
Scientific paper
Here we present an angle-resolved photoelectron spectroscopy (ARPES), x-ray absorption spec-troscopy (XAS), and density-functional theory (DFT) investigations of water and ammonia ad-sorption on graphene/Ni(111). Our results on graphene/Ni(111) reveal the existence of interface states, originating from the strong hybridization of the graphene {\pi} and spin-polarized Ni 3d valence band states. ARPES and XAS data of the H2O (NH3)/graphene/Ni(111) system give an information about the kind of interaction between adsorbed molecules and graphene on Ni(111). The presented experimental data are compared with the results obtained in the framework of the DFT approach.
Boettcher Stefan
Dedkov Yu. S.
Horn Karsten
Paulus Beate
Voloshina E. N.
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