Physics – Condensed Matter – Soft Condensed Matter
Scientific paper
2012-03-29
Physics
Condensed Matter
Soft Condensed Matter
accepted for publication in Soft Matter
Scientific paper
We study the crystallization of a colloidal model system in presence of secondary nanoparticles acting as impurities. Using confocal microscopy, we show that the nanoparticles segregate in the grain boundaries of the colloidal polycrystal. We demonstrate that the texture of the polycrystal can be tuned by varying independently the nanoparticle volume fraction and the crystallization rate, and quantify our findings using standard models for the nucleation and growth of crystalline materials. Remarkably, we find that the efficiency of the segregation of the nanoparticles in the grain-boundaries is determined solely by the typical size of the crystalline grains.
Cipelletti Luca
Ghofraniha Neda
Oberdisse Julian
Ramos Laurence
Tamborini Elisa
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