Physics – Condensed Matter – Materials Science
Scientific paper
2005-03-31
Phys. Rev. Lett. 95, 125503 (2005)
Physics
Condensed Matter
Materials Science
4+ pages, 4 figures. Updated figures and text. Accepted to PRL
Scientific paper
10.1103/PhysRevLett.95.125503
We have measured the polarized Raman scattering spectra of Cd2Re2O7, the first superconducting pyrochlore, as a function of temperature. For temperatures below the cubic-to-tetragonal structural phase transition (SPT) at 200K, a peak with B1 symmetry develops at zero frequency with divergent intensity. We identify this peak as the first observation of the Goldstone phonon in a crystalline solid. The Goldstone phonon is a collective excitation that exists due to the breaking of the continuous symmetry with the SPT. Its emergence coincides with that of a Raman-active soft mode. The order parameter for both features derives from an unstable doubly-degenerate vibration (with Eu symmetry) of the O1 atoms which drives the SPT.
He Jingsong
Jin Rongying
Kendziora C. A.
Keppens Veerle
Mandrus David
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