Physics – Condensed Matter – Strongly Correlated Electrons
Scientific paper
2005-04-18
Phys. Rev. B 72, 054411 (2005)
Physics
Condensed Matter
Strongly Correlated Electrons
17 pages, 5 figures, submitted to Phys Rev B; added acknowledgements
Scientific paper
10.1103/PhysRevB.72.054411
We have characterized the magnetic and structural properties of the CdLn2Se4 (Ln = Dy, Ho), and CdLn2S4 (Ln = Ho, Er, Tm, Yb) spinels. We observe all compounds to be normal spinels, possessing a geometrically frustrated sublattice of lanthanide atoms with no observable structural disorder. Fits to the high temperature magnetic susceptibilities indicate these materials to have effective antiferromagnetic interactions, with Curie-Weiss temperatures theta ~ -10 K, except CdYb2S4 for which theta ~ -40 K. The absence of magnetic long range order or glassiness above T = 1.8 K strongly suggests that these materials are a new venue in which to study the effects of strong geometrical frustration, potentially as rich in new physical phenomena as that of the pyrochlore oxides.
Cava Robert. J.
Freitas Rafael S.
Lau G. C.
Schiffer Peter
Ueland Benjamin G.
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