Physics – Condensed Matter – Statistical Mechanics
Scientific paper
2010-07-28
The Journal of Chemical Physics 133, 134101 (2010)
Physics
Condensed Matter
Statistical Mechanics
15 pages, 4 figures
Scientific paper
10.1063/1.3496468
In this paper we apply the global isomorphism approach [V.~L. Kulinskii, J. Phys. Chem. B \textbf{114} 2852 (2010)] between the Lennard-Jones fluids and Lattice Gas model to the study of the liquid-vapor equilibrium for the systems with the short-ranged potentials like Buckingham and the $Mie$-potentials. The estimates for the critical point locus correlate quite well with the available numerical data. Also within the proposed approach we give the explanation for the correlation between the value of the second virial coefficient at the critical temperature and the particle volume found in [G. A. Vliegenthart and H. N. W. Lekkerkerker, J. Chem. Phys. \textbf{112} 5364 (2000)].
Bulavin Leonid
Kulinskii Vladimir
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