Free Energy Formalism for Particle Adsorption

Details Free Energy Formalism for Particle Adsorption Free Energy Formalism for Particle Adsorption

2005-02-04

arxiv.org/abs/cond-mat/0502135v1

Physical Review E 71 (2005) 031101

Physics

Condensed Matter

Soft Condensed Matter

to be published in Physical Review E

Scientific paper

10.1103/PhysRevE.71.031101

The equilibrium properties of particles adsorption is investigated theoretically. The model relies on a free energy formulation which allows to generalize the Maxwell-Boltzmann description to solutions for which the bulk volume fraction of potentially adsorbed particles is very high. As an application we consider the equilibrium physical adsorption of neutral and charged particles from solution onto two parallel adsorbing surfaces.

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