Physics – Condensed Matter – Mesoscale and Nanoscale Physics
Scientific paper
2009-10-28
Physics
Condensed Matter
Mesoscale and Nanoscale Physics
9 pages, 5 figures
Scientific paper
On the example of a particular problem, the theory of vacancies, a new form of kinetic equations symmetrically incorporation the internal and free energies has been derived. The dynamical nature of irreversible phenomena at formation and motion of defects (dislocations) has been analyzed by a computer experiment. The obtained particular results are extended into a thermodynamic identity involving the law of conservation of energy at interaction with an environment (the 1st law of thermodynamics) and the law of energy transformation into internal degree of freedom (relaxation). The identity is compared with the analogous Jarzynski identity. The approach is illustrated by simulation of processes during severe plastic deformation, the Rybin kinetic equation for this case has been derived.
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