Physics – Condensed Matter – Materials Science
Scientific paper
2010-11-16
Nature Commun. 1: 118 (2010)
Physics
Condensed Matter
Materials Science
21 pages, 12 figures
Scientific paper
10.1038/ncomms1112
Here we demonstrate that water-infiltrated nanoporous glass electrically switches an oxide semiconductor from an insulator to metal. We fabricated the field effect transistor structure on an oxide semiconductor, SrTiO3, using 100%-water-infiltrated nanoporous glass - amorphous 12CaO*7Al2O3 - as the gate insulator. For positive gate voltage, electron accumulation, water electrolysis and electrochemical reduction occur successively on the SrTiO3 surface at room temperature, leading to the formation of a thin (~3 nm) metal layer with an extremely high electron concentration of 10^15-10^16 cm^-2, which exhibits exotic thermoelectric behaviour.
Hosono Hideo
Ikuhara Yuichi
Kato Takeharu
Kim Sung-Wng
Nomura Kenji
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