Physics – Condensed Matter – Strongly Correlated Electrons
Scientific paper
2003-04-09
Physics
Condensed Matter
Strongly Correlated Electrons
Accepted of publication in Europhysics Letters, 11 pages, 5 figures
Scientific paper
10.1209/epl/i2003-00414-0
Magnetic anisotropy has been measured for the ferromagnetic La0.7Sr0.3CoO3 perovskite from an analysis of the high-field part of the magnetization vs. field curves, i.e., the magnetic saturation regime. These measurements give a magnetic anistropy one order of magnitude higher than that of reference manganites. Surprisingly, the values of the magnetic anisotropy calculated in this way do not coincide with those estimated from measurements of coercive fields which are one order of magnitude smaller. It is proposed that the reason of this anomalous behaviour is a transition of the trivalent Co ions under the external magnetic field from a low-spin to an intermediate-spin state. Such a transition converts the Co3+ ions into Jahn-Teller ions having an only partially quenched orbital angular momentum, which enhances the intra-atomic spin-orbit coupling and magnetic anisotropy.
Caciuffo R.
Ibarra M. R.
Mira Jorge
Rivas J.
Senaris Rodriguez M. A.
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